RAC

Which class of refrigerants has the highest Ozone Depletion Potential (ODP)?

  • HFCs
  • HCFCs
  • CFCs
  • Natural Refrigerants

Explanation:

  • HFCs have zero ODP but high GWP.
  • HCFCs have a medium ODP (e.g., R-22 ODP=0.055).
  • CFCs have the highest ODP (e.g., R-11 ODP=1.0, R-12 ODP=0.82).
  • Natural refrigerants like CO2 or Ammonia have zero ODP.

What is the chemical formula for the commonly used CFC refrigerant R-12?

  • CHClF₂
  • CCl₄
  • CCl₂F₂
  • C₂H₂F₄

Explanation:

  • CHClF₂ is the formula for HCFC-22 (R-22).
  • CCl₄ is carbon tetrachloride.
  • CCl₂F₂ is the correct formula for Dichlorodifluoromethane (R-12).
  • C₂H₂F₄ is not a standard refrigerant formula.

Which protocol is the landmark international treaty designed to protect the ozone layer?

  • Kyoto Protocol
  • Paris Agreement
  • Montreal Protocol
  • Geneva Convention

Explanation:

  • The Kyoto Protocol deals with greenhouse gas emissions.
  • The Paris Agreement focuses on climate change mitigation.
  • The Montreal Protocol on Substances that Deplete the Ozone Layer was agreed upon in 1987.
  • The Geneva Convention relates to the treatment of war victims.

HFC refrigerants are considered harmful because they have:

  • High Ozone Depletion Potential
  • High toxicity and flammability
  • High Global Warming Potential
  • All of the above

Explanation:

  • HFCs have zero ODP.
  • Most common HFCs like R-134a are non-toxic and non-flammable (A1 safety class).
  • HFCs have high Global Warming Potential (e.g., R-134a GWP = 1430). This is their primary environmental concern.
  • Only High GWP is correct.

According to India’s HCFC phase-out schedule, the complete phase-out of HCFC-22 (R-22) is targeted by which year?

  • 2020
  • 2025
  • 2030
  • 2040

Explanation:

  • 2020 was the year for a freeze and 67.5% reduction.
  • 2025 is the year for a 90% reduction.
  • 2030 is the target for a complete phase-out of HCFCs in India, as per the Montreal Protocol.
  • 2040 is not a milestone year for India’s HCFC phase-out.

Which of the following is a common HFC refrigerant used as a replacement for R-12 in automotive air conditioning?

  • R-22
  • R-134a
  • R-410A
  • R-502

Explanation:

  • R-22 is an HCFC used in stationary AC systems.
  • R-134a (HFC-134a) became the standard replacement for CFC-12 (R-12) in automotive AC.
  • R-410A is an HFC blend used as an R-22 replacement in new residential AC units.
  • R-502 was a CFC/HCFC blend used in commercial refrigeration.

The “Ozone Rules” in India are officially known as:

  • The Environment Protection Act, 1986
  • The Ozone Depleting Substances (Regulation and Control) Rules, 2000
  • The Montreal Protocol Implementation Act
  • The Air Prevention and Control of Pollution Act

Explanation:

  • A broader act for environmental protection.
  • This is the correct official name for the “Ozone Rules” notified under the Environment Protection Act.
  • This is not the name of the Indian legislation.
  • This act deals with air pollution in general.

Which property of a refrigerant is indicated by its ASHRAE safety classification ‘A2L’?

  • Lower toxicity and higher flammability
  • Higher toxicity and lower flammability
  • Lower toxicity and lower flammability
  • Lower toxicity and mild flammability

Explanation:

  • Describes Class B2 or B2L refrigerants.
  • Describes Class B1 refrigerants.
  • Describes Class A1 refrigerants (e.g., R-134a, R-410A).
  • ‘A’ means lower toxicity. ‘2L’ means the refrigerant is mildly flammable with a burning velocity less than 10 cm/s. (e.g., R-32).

What is the chemical name for the HCFC refrigerant R-22?

  • Dichlorodifluoromethane
  • Chlorodifluoromethane
  • Chlorofluoromethane
  • Trifluoromethane

Explanation:

  • This is the name for R-12, a CFC.
  • This is the correct name for R-22 (HCFC-22).
  • Not a standard refrigerant.
  • This is the name for R-23, an HFC.

The Kigali Amendment to the Montreal Protocol deals with the phase-down of:

  • CFCs
  • HCFCs
  • HFCs
  • All Halocarbons

Explanation:

  • CFCs were already addressed by the original protocol.
  • HCFCs are being phased out under earlier amendments.
  • The Kigali Amendment (2016) aims to phase down the production and consumption of HFCs due to their high GWP.
  • It specifically targets HFCs.

Which of these is a natural refrigerant with zero ODP and negligible GWP?

  • R-407C
  • R-600a
  • R-404A
  • R-508B

Explanation:

  • R-407C is an HFC blend with high GWP.
  • R-600a (Isobutane) is a hydrocarbon, a natural refrigerant with ODP=0 and GWP≈3.
  • R-404A is an HFC blend with very high GWP (≈3922).
  • R-508B is an HFC/HCFC blend.

The number in a refrigerant designation (e.g., R-134) is derived from:

  • Its boiling point in °C
  • Its molecular weight
  • A code indicating its chemical composition
  • Its year of discovery

Explanation:

  • It is not directly related to the boiling point.
  • It is not the molecular weight.
  • The numbering system is based on a rule: For methane/ethane series, the number indicates the number of Carbon, Hydrogen, and Fluorine atoms.
  • It is not related to the year.

Which organization is responsible for assigning standard safety classifications (like A1, B2L) to refrigerants?

  • ISO
  • ASHRAE
  • UNEP
  • EPA

Explanation:

  • ISO adopts standards but is not the primary source.
  • ASHRAE Standard 34 designates the safety classification of refrigerants.
  • UNEP oversees the Montreal Protocol.
  • EPA sets regulations in the USA.

What does the ‘a’ suffix in R-134a signify?

  • It is an azeotropic mixture
  • It is an isomer with different atomic arrangement
  • It is an atmospheric refrigerant
  • It is an additive mixture

Explanation:

  • Azeotropic mixtures have a suffix like R-500.
  • The suffix (a, b, c) indicates different isomers. R-134 and R-134a have the same formula (C₂H₂F₄) but different atomic structures and properties.
  • This is not a standard meaning.
  • This is not a standard meaning.

Which of these is NOT a property considered when selecting a refrigerant?

  • Latent heat of vaporization
  • Coefficient of Performance (COP)
  • Color of the refrigerant
  • Operating pressures

Explanation:

  • High latent heat is desirable for higher capacity.
  • COP is a key performance indicator.
  • The color of a refrigerant is not a functional property. Refrigerants are typically colorless.
  • Operating pressures dictate system design and strength requirements.

The primary function of a refrigerant in a vapor compression cycle is to:

  • Absorb heat during evaporation and reject heat during condensation
  • Lubricate the compressor
  • Clean the system components
  • Increase the pressure of the system

Explanation:

  • This is the fundamental principle of the refrigeration cycle.
  • This is the function of the lubricating oil.
  • Refrigerants do not clean the system.
  • The compressor increases the pressure; the refrigerant is the working fluid.

Which CFC was most commonly used in domestic refrigerators before the phase-out?

  • R-11
  • R-12
  • R-113
  • R-502

Explanation:

  • R-11 was used as a blowing agent for insulation foam and in large chillers.
  • R-12 was the most common refrigerant for domestic refrigerators and automotive AC.
  • R-113 was used as a solvent.
  • R-502 was used in commercial low-temperature refrigeration.

The Montreal Protocol is often cited as a successful example of:

  • International trade agreement
  • Global environmental cooperation
  • Military alliance
  • Economic sanctions

Explanation:

  • Its primary goal is not trade.
  • It is universally ratified and has successfully slowed ozone depletion through global cooperation.
  • It is not a military agreement.
  • It uses phase-out schedules, not sanctions.

Which of these is a zeotropic refrigerant blend?

  • R-502
  • R-407C
  • R-500
  • R-12

Explanation:

  • R-502 is an azeotropic blend.
  • R-407C is a zeotropic blend of HFCs (R-32, R-125, R-134a) with a temperature glide.
  • R-500 is an azeotropic blend.
  • R-12 is a single-component refrigerant.

The “Ozone Depletion Potential” (ODP) of a refrigerant is measured relative to:

  • Carbon Dioxide (CO₂)
  • Ammonia (R-717)
  • Trichlorofluoromethane (R-11)
  • Water

Explanation:

  • CO₂ is the reference for GWP (GWP=1).
  • Ammonia has an ODP of 0.
  • R-11 is assigned a baseline ODP of 1.0. All other ODP values are relative to it.
  • Water is not a reference for ODP.

What major environmental issue are HFC refrigerants primarily associated with?

  • Acid Rain
  • Ozone Layer Depletion
  • Climate Change / Global Warming
  • Smog Formation

Explanation:

  • Caused mainly by SO₂ and NOx emissions.
  • HFCs have zero ODP and do not deplete the ozone layer.
  • HFCs are potent greenhouse gases with high Global Warming Potential (GWP), contributing to climate change.
  • Caused by ground-level ozone and particulates, not directly by HFCs.

Which hydrocarbon refrigerant is commonly used in modern domestic refrigerators?

  • R-290 (Propane)
  • R-600a (Isobutane)
  • R-1270 (Propylene)
  • R-50 (Methane)

Explanation:

  • R-290 is used in commercial systems and heat pumps.
  • R-600a (Isobutane) is the most common hydrocarbon refrigerant used in domestic refrigerators today.
  • R-1270 is used in industrial applications.
  • R-50 is not practical for domestic refrigeration.

The phase-out of CFCs in developed countries was mostly completed by:

  • 1990
  • 1996
  • 2000
  • 2010

Explanation:

  • 1990 was a target for a freeze.
  • Developed countries phased out major CFCs like R-11 and R-12 by 1996 under the Montreal Protocol.
  • 2000 was a milestone for some HCFCs.
  • 2010 was a milestone for HCFCs in developed countries.

Which of these is a primary requirement for a “drop-in” refrigerant replacement?

  • It must be the same color as the original
  • It must require no changes to the existing system
  • It must be cheaper than the original
  • It must be natural

Explanation:

  • Color is irrelevant.
  • A “drop-in” replacement is intended to work in an existing system with minimal changes, though some (like oil change) are often needed.
  • Cost is a factor but not the defining requirement.
  • Many drop-in replacements are synthetic blends.

The Ozone Depleting Substances (Regulation and Control) Rules, 2000 in India are administered by the:

  • Ministry of Power
  • Ministry of Road Transport and Highways
  • Ministry of Environment, Forest and Climate Change (MoEF&CC)
  • Ministry of Chemicals and Fertilizers

Explanation:

  • Not responsible for environmental regulations.
  • Not responsible for environmental regulations.
  • The MoEF&CC is the nodal ministry for implementing the Montreal Protocol and related rules like the ODS Rules, 2000.
  • Not the nodal ministry for ODS rules.
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